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Alodine and Zinc Chromate, Part II

 
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messydeer



Joined: 13 Feb 2006
Posts: 214
Location: Bellingham, WA

PostPosted: Mon Jul 03, 2006 11:46 am    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Hi!

I spent most of yesterday etching my VS parts with Alumiprep. I draped a vinyl shower curtain across my table w/ 2x4's underneath around the edges. Things went pretty well. Aluminum fizzed and turned sorta white.

After draining and rinsing the drape well, I put in Alodine, 1:2 w/ water as suggested in their literature. Used cheesecloth to drape over areas that stuck out above the bath and kept it pretty moist. I was dissappointed with the results. Even after leaving parts in their for 15 minutes, there was little color change.

I tackled it again today and added straight Alodine 1201 to the old bath, making the solution maybe 1:1. That seemed to do the trick. Only took 5 minutes for the desired color change. But I did notice the 2nd batch of parts took longer to change. I might also mention the original 1:2 bath was recycled from my first session a month ago. Although Henkel says you can re-use the solution, it seems fresh Alodine does a much better job.

But even with the fresh concentrated solution, I still got some patchiness. I did prep well: dish soap solution sprayed on and scoured w/ scotchbrite; rinse w/ water; wipe w/ lacquer thinner; kept fingerprints off parts.

Right now I've sprayed all with the first coat of zinc chromate (tempo cans). Alodine is supposed to help promote adhesion of the primer. Given the patchiness of its coat and the hassle with its application, I'm considering just acid etching and then zinc chromate without Alodine. How does this sound to you zinc chromaters?

Thanks,
Dan[/b]


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PostPosted: Mon Jul 03, 2006 12:38 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

    I live in the wet jungles of Oregon, and very few builders here are going to the trouble of Etching, Alodine, and Zinc.  Nearly everyone is using Zinc Chromate on mating surfaces, but many of those builders are just using a scotchbrite pad to rough the surface prior to spraying.  With more rainy and wet days than sunny, the aircraft are still exhibiting very good corrosion resistance when using 6061-T6.  Note that the important part of that sentence is the "T6-6061" part.
    If you're using a less corrosion resistant type of aluminum (2024-T3 is common) you'll want to do all you can to prolong the life of the aircraft.  6061-T6 will still benefit from the Etch, Alodine, Zinc process, but already exhibits excellent corrosion resistance (due in part to being artificially aged during the production porocess).

messydeer <messydeer(at)yahoo.com> wrote:[quote] --> Zenith-List message posted by: "messydeer"

Hi!

I spent most of yesterday etching my VS parts with Alumiprep. I draped a vinyl shower curtain across my table w/ 2x4's underneath around the edges. Things went pretty well. Aluminum fizzed and turned sorta white.

After draining and rinsing the drape well, I put in Alodine, 1:2 w/ water as suggested in their literature. Used cheesecloth to drape over areas that stuck out above the bath and kept it pretty moist. I was dissappointed with the results. Even after leaving parts in their for 15 minutes, there was little color change.

I tackled it again today and added straight Alodine 1201 to the old bath, making the solution maybe 1:1. That seemed to do the trick. Only took 5 minutes for the desired color change. But I did notice the 2nd batch of parts took longer to change. I might also mention the original


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PostPosted: Mon Jul 03, 2006 1:13 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Dan,
 
Not to get another scotchbrite and primer debate going, I just used the scotchbrite and cleaned with lacquer thinner and sprayed with self etching primer and have had great results.
 
Bob Spudis
N701ZX  701/912S
 
do not archive
 
 
 
 
 
 
In a message dated 7/3/2006 3:49:03 P.M. Eastern Daylight Time, messydeer(at)yahoo.com writes:
Quote:
Hi!

I spent most of yesterday etching my VS parts with Alumiprep. I draped a vinyl shower curtain across my table w/ 2x4's underneath around the edges. Things went pretty well. Aluminum fizzed and turned sorta white.

After draining and rinsing the drape well, I put in Alodine, 1:2 w/ water as suggested in their literature. Used cheesecloth to drape over areas that stuck out above the bath and kept it pretty moist. I was dissappointed with the results. Even after leaving parts in their for 15 minutes, there was little color change.

I tackled it again today and added straight Alodine 1201 to the old bath, making the solution maybe 1:1. That seemed to do the trick. Only took 5 minutes for the desired color change. But I did notice the 2nd batch of parts took longer to change. I might also mention the original 1:2 bath was recycled from my first session a month ago. Although Henkel says you can re-use the solution, it seems fresh Alodine does a much better job.

But even with the fresh concentrated solution, I still got some patchiness. I did prep well: dish soap solution sprayed on and scoured w/ scotchbrite; rinse w/ water; wipe w/ lacquer thinner; kept fingerprints off parts.

Right now I've sprayed all with the first coat of zinc chromate (tempo cans). Alodine is supposed to help promote adhesion of the primer. Given the patchiness of its coat and the hassle with its application, I'm considering just acid etching and then zinc chromate without Alodine. How does this sound to you zinc chromaters?

Thanks,
Dan[/b]

--------
Dan


 


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Crvsecretary(at)aol.com
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PostPosted: Mon Jul 03, 2006 1:49 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Hello Bob and Listers:
 
I used the scotchbrite/lacquer thinner/rattle can approach for the horizontal stabilizer, elevator, flaps, and ailerons with acceptable results.  I have two questions for everyone:
 
1) The scotchbrite pad thing seems to take forever by hand.  I'm using a plain old scotchbrite pad (number and color to remain nameless so as not to incite another Scotchbrite debate) and rubbing the parts to take the shine off them.  Is there an easier way?  A wheel or something to make the job move along?
 
2) I've just started priming the wing ribs using a scotchbrite/lacquer thinner/two-part epoxy primer.  WOW - this stuff REALLY sticks !!!!  I like it - but it's a lot of work.  Is anyone else using a two-part epoxy primer?
 
Tracy Smith
Naugatuck, CT
601xl N458XL (reserved)
do not archive

 
 
 
In a message dated 7/3/2006 5:14:29 PM Eastern Standard Time, NYTerminat(at)aol.com writes:
Quote:
Dan,
 
Not to get another scotchbrite and primer debate going, I just used the scotchbrite and cleaned with lacquer thinner and sprayed with self etching primer and have had great results.
 
Bob Spudis
N701ZX  701/912S
 
do not archive
 
 
 
 
 
 
In a message dated 7/3/2006 3:49:03 P.M. Eastern Daylight Time, messydeer(at)yahoo.com writes:
Quote:
Hi!

I spent most of yesterday etching my VS parts with Alumiprep. I draped a vinyl shower curtain across my table w/ 2x4's underneath around the edges. Things went pretty well. Aluminum fizzed and turned sorta white.

After draining and rinsing the drape well, I put in Alodine, 1:2 w/ water as suggested in their literature. Used cheesecloth to drape over areas that stuck out above the bath and kept it pretty moist. I was dissappointed with the results. Even after leaving parts in their for 15 minutes, there was little color change.

I tackled it again today and added straight Alodine 1201 to the old bath, making the solution maybe 1:1. That seemed to do the trick. Only took 5 minutes for the desired color change. But I did notice the 2nd batch of parts took longer to change. I might also mention the original 1:2 bath was recycled from my first session a month ago. Although Henkel says you can re-use the solution, it seems fresh Alodine does a much better job.

But even with the fresh concentrated solution, I still got some patchiness. I did prep well: dish soap solution sprayed on and scoured w/ scotchbrite; rinse w/ water; wipe w/ lacquer thinner; kept fingerprints off parts.

Right now I've sprayed all with the first coat of zinc chromate (tempo cans). Alodine is supposed to help promote adhesion of the primer. Given the patchiness of its coat and the hassle with its application, I'm considering just acid etching and then zinc chromate without Alodine. How does this sound to you zinc chromaters?

Thanks,
Dan[/b]

--------
Dan


 


 
 
 


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PostPosted: Mon Jul 03, 2006 2:14 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

3M makes a Roloc disk for use with a 90-degree die grinder.  You can get it in any flavor of standard scotch-brite pad.  Be carefull with your RPMS.  It will eat right through your .020 skins if you're too high!

   

Crvsecretary(at)aol.com wrote:
Quote:
Hello Bob and Listers:
 
I used the scotchbrite/lacquer thinner/rattle can approach for the horizontal stabilizer, elevator, flaps, and ailerons with acceptable results.  I have two questions for everyone:
 
1) The scotchbrite pad thing seems to take forever by hand.  I'm using a plain old scotchbrite pad (number and color to remain nameless so as not to incite another Scotchbrite debate) and rubbing the parts to take the shine off them.  Is there an easier way?  A wheel or something to make the job move along?
 
2) I've just started priming the wing ribs using a scotchbrite/lacquer thinner/two-part epoxy primer.  WOW - this stuff REALLY sticks !!!!  I like it - but it's a lot of work.  Is anyone else using a two-part epoxy primer?
 
Tracy Smith
Naugatuck, CT
601xl N458XL (reserved)
do not archive

 
 
 
In a message dated 7/3/2006 5:14:29 PM Eastern Standard Time, NYTerminat(at)aol.com writes:
Quote:
Dan,
 
Not to get another scotchbrite and primer debate going, I just used the scotchbrite and cleaned with lacquer thinner and sprayed with self etching primer and have had great results.
 
Bob Spudis
N701ZX  701/912S
 
do not archive
 
 
 
 
 
 
In a message dated 7/3/2006 3:49:03 P.M. Eastern Daylight Time, messydeer(at)yahoo.com writes:
Quote:
Hi!

I spent most of yesterday etching my VS parts with Alumiprep. I draped a vinyl shower curtain across my table w/ 2x4's underneath around the edges. Things went pretty well. Aluminum fizzed and turned sorta white.

After draining and rinsing the drape well, I put in Alodine, 1:2 w/ water as suggested in their literature. Used cheesecloth to drape over areas that stuck out above the bath and kept it pretty moist. I was dissappointed with the results. Even after leaving parts in their for 15 minutes, there was little color change.

I tackled it again today and added straight Alodine 1201 to the old bath, making the solution maybe 1:1. That seemed to do the trick. Only took 5 minutes for the desired color change. But I did notice the 2nd batch of parts took longer to change. I might also mention the original 1:2 bath was recycled from my first session a month ago. Although Henkel says you can re-use the solution, it seems fresh Alodine does a much better job.

But even with the fresh concentrated solution, I still got some patchiness. I did prep well: dish soap solution sprayed on and scoured w/ scotchbrite; rinse w/ water; wipe w/ lacquer thinner; kept fingerprints off parts.

Right now I've sprayed all with the first coat of zinc chromate (tempo cans). Alodine is supposed to help promote adhesion of the primer. Given the patchiness of its coat and the hassle with its application, I'm considering just acid etching and then zinc chromate without Alodine. How does this sound to you zinc chromaters?

Thanks,
Dan[/b]

--------
Dan


 


 
 
 


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randy(at)shadycreekoutlaw
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PostPosted: Mon Jul 03, 2006 2:54 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Afix the scotchbrite pad to a vibrating or random orbital sander...  This will should help.
 
Randy
XL Wings - Plans Only
http://www.n344rb.com
Do Not Archive
 
[quote] ---


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PostPosted: Mon Jul 03, 2006 4:31 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Did you do a water break test? Spray a little clean water on the prepared
aluminium and it should coat the aluminium without any breaks in the
water... Then it's ready for the Alodine. I've used Alodine several times
without the splochyness you describe.

Noel

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PostPosted: Mon Jul 03, 2006 4:55 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

--- Crvsecretary(at)aol.com wrote:

Quote:

Hello Bob and Listers:

I used the scotchbrite/lacquer thinner/rattle can
approach for the
horizontal stabilizer, elevator, flaps, and ailerons
with acceptable results. I have
two questions for everyone:

1) The scotchbrite pad thing seems to take forever
by hand. I'm using a
plain old scotchbrite pad (number and color to
remain nameless so as not to
incite another Scotchbrite debate) and rubbing the
parts to take the shine off
them. Is there an easier way? A wheel or something
to make the job move along?

2) I've just started priming the wing ribs using a
scotchbrite/lacquer
thinner/two-part epoxy primer. WOW - this stuff
REALLY sticks !!!! I like it -
but it's a lot of work. Is anyone else using a
two-part epoxy primer?


Tracy Smith
Naugatuck, CT
601xl N458XL (reserved)
do not archive




Tracy.


I used the two part epoxy on the entire airplane
inside. Alumaprep/alodine then prime. Yes it was a
lot of work. I let the alumaprep do all the work of
dulling the surface. I mixed some 409 cleaner in with
the full strength alumaprep to do two steps in one. I
cleaned it with thinner first to get off the ink, then
let the alumaprep do its thing.

I know a lot of people say there is no need to go to
all this work, that 6061 will outlast all of us.
Maybe so, but I had a 1964 C-150 that was paper thin
because of corrosion after thirty years and never by
the ocean. Yeah I know it was 2024 not 6061. But the
2024 they use has an almost pure aluminum layer clad
on it, this is way more corrosion resistant than 6061.
Where did all that pure aluminum go?

I figure that some new owner of my plane thirty years
from now will look inside at no corrosion and say WOW
did this guy really know how to build an airplane.
Worth every extra hour I put into it.

Although I must confess that I found a place called
Pacific Coast Anodizing that did what the industry
calls Chem-film, (alumaprep/alodine)that did all of
both wing parts (ribs,skins,spars all little parts)
for $75.00 and the entire fuse and tail parts for
another $125.00 for me. I got them back individually
wrapped in paper, picked up and delivered to my door.
Not bad if you live in the central valley of
California.

Keep up the good work I think it is worth it.

Mark S.
701/912S
Paint booth built
painting

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messydeer



Joined: 13 Feb 2006
Posts: 214
Location: Bellingham, WA

PostPosted: Mon Jul 03, 2006 6:52 pm    Post subject: Re: Alodine and Zinc Chromate, Part II Reply with quote

Thanks everybody for the feedback :=)

Quote:
The scotchbrite pad thing seems to take forever by hand.? I'm using a plain old scotchbrite pad


Ditto w/ the dual action scotchbrite, especially w/ skins, since the pad is ~6" across. I have a weanie compressor so it's not time efficient for me.

Quote:
Did you do a water break test?


Well...uh...no...Knew about it but didn't do it. I did notice the water ran off easily in sheets, but should have thoroughly tested.

Quote:
jungles of Oregon


I'm in similar jungles of the former Oregon Territory. Before that the city was named by George Vancouver after the controller of the storekeeper's account of the Royal Navy. Juding from that, I presume it to have been one of the last things he named.

Cheers,
Dan


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PostPosted: Mon Jul 03, 2006 7:56 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Tracy,
I found that it was not bad using the pad by hand. I know that there are scotchbrite wheels that are available but I did not use them. I found that when the pad took longer to use I got rid of it and used a new one. They weren't all that expensive and the new one worked much faster.
 
In a message dated 7/3/2006 5:50:25 P.M. Eastern Daylight Time, Crvsecretary(at)aol.com writes:
Quote:
The scotchbrite pad thing seems to take forever by hand.  I'm using a plain old scotchbrite pad (number and color to remain nameless so as not to incite another Scotchbrite debate) and rubbing the parts to take the shine off them.  Is there an easier way?  A wheel or something to make the job move along?


 


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messydeer



Joined: 13 Feb 2006
Posts: 214
Location: Bellingham, WA

PostPosted: Mon Jul 03, 2006 8:13 pm    Post subject: Re: Alodine and Zinc Chromate, Part II Reply with quote

Enco sells the maroon 7447 scotchbrite for $.59 per pad. I don't use one, but they also have on sale scotchbrite wheels. Order more than $50 and you can get shipping free if you use the code WEBRN76 Their site is www.use-enco.com. They ship fast, are fairly cheap and have excellent customer service.

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PostPosted: Tue Jul 04, 2006 4:28 am    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Mark:

I congratulate you on using the Alodine and zinc chromate. I think the
epoxy base is a bit of overkill if you aren't going to try to stick cloth
over it but as you say it will stick!!

If you really want pure aluminium and I don't think you really do, its
available in sheets from the folks who make aluminium doors etc. You will
find pure aluminium isn't nearly as corrosion resistant as alumiclad 6061.
You will also find it has the strength a little greater than wet toilet
paper and rivets won't stay tight in it.

Did you alodine both sides of your skins? Doing so protects the skins under
the nice urethane paints and primers.

Noel

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PostPosted: Tue Jul 04, 2006 6:22 am    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Noel.

No where in my post did I say to use pure aluminum.
What I said is that pure aluminum is clad to 2024 to
make it more corrosion resistant. So the pure aluminum
coating is more corrosion resistant than bare 6061 or
2024. That is why most certified aircraft use 2024
alclad, they get the strength of 2024 and the
corrosion protection of the pure aluminum clad.

Mark S.

--- Noel Loveys <noelloveys(at)yahoo.ca> wrote:

[quote]
<noelloveys(at)yahoo.ca>

Mark:

I congratulate you on using the Alodine and zinc
chromate. I think the
epoxy base is a bit of overkill if you aren't going
to try to stick cloth
over it but as you say it will stick!!

If you really want pure aluminium and I don't think
you really do, its
available in sheets from the folks who make
aluminium doors etc. You will
find pure aluminium isn't nearly as corrosion
resistant as alumiclad 6061.
You will also find it has the strength a little
greater than wet toilet
paper and rivets won't stay tight in it.

Did you alodine both sides of your skins? Doing so
protects the skins under
the nice urethane paints and primers.

Noel



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PostPosted: Tue Jul 04, 2006 6:57 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

Sorry I misunderstood you.

Noel

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PostPosted: Wed Jul 05, 2006 2:18 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

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PostPosted: Wed Jul 05, 2006 3:15 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

    Your statements are basically correct John.  6061-T6 is 'slightly' less corrosion resistant than 2024 clad in pure aluminum (very slightly so). Keep in mind that the layer of pure aluminum is sometimes only a few atoms thick.  this shouldn't be of any concern if you're painting your aircraft.  If you're going to polish the aluminum and leave it bare, that layer will eventually become thin enough as to warrant corrosion treatment and painting.  I understand that several good products exist specifically to provide extended protection to polished aluminum aircraft, although I've never used any of them.
    If you were able to find 6061-T6 with a layer of pure aluminum, you'd get the best of both worlds.  Good luck on that one.  It's not necessary, so it's not available...

Tom Henderson
601XL Fuse
A few weeks from completion, FINALLY!

McMinnville, Oregon
503-474-3882


John Bolding <jnbolding1(at)teleshare.net> wrote:[quote] --> Zenith-List message posted by: "John Bolding"
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PostPosted: Wed Jul 05, 2006 6:56 pm    Post subject: Alodine and Zinc Chromate, Part II Reply with quote

It is my understanding that for corrosion to occur there are two things
required moisture and a source of oxygen. Pure aluminium is very porous as
it corrodes this porosity will hold moisture which speeds up the corrosion
process. Alumiclad, as I understand it, allows a thin layer of oxidation to
occur that is not thick enough to be porous just thick enough to isolate
the underlying alloys from a source of oxygen.

Noel

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